Researchers grow precise arrays of nanoLEDs
A new technique produces perovskite nanocrystals right where they're
needed, so the exceedingly delicate materials can be integrated into nanoscale devices.

Date:
July 6, 2023
Source:
Massachusetts Institute of Technology
Summary:
A new platform enables researchers to 'grow' halide perovskite
nanocrystals with precise control over the location and size
of each individual crystal, integrating them into nanoscale
light-emitting diodes.


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FULL STORY ========================================================================== Halide perovskites are a family of materials that have attracted attention
for their superior optoelectronic properties and potential applications
in devices such as high-performance solar cells, light-emitting diodes,
and lasers.

These materials have largely been implemented into thin-film or
micron-sized device applications. Precisely integrating these materials
at the nanoscale could open up even more remarkable applications, like
on-chip light sources, photodetectors, and memristors. However, achieving
this integration has remained challenging because this delicate material
can be damaged by conventional fabrication and patterning techniques.

To overcome this hurdle, MIT researchers created a technique that
allows individual halide perovskite nanocrystals to be grown on-site
where needed with precise control over location, to within less than 50 nanometers. (A sheet of paper is 100,000 nanometers thick.) The size of
the nanocrystals can also be precisely controlled through this technique,
which is important because size affects their characteristics. Since
the material is grown locally with the desired features, conventional lithographic patterning steps that could introduce damage are not needed.

The technique is also scalable, versatile, and compatible with
conventional fabrication steps, so it can enable the nanocrystals to be integrated into functional nanoscale devices. The researchers used this
to fabricate arrays of nanoscale light-emitting diodes (nanoLEDs) --
tiny crystals that emit light when electrically activated. Such arrays
could have applications in optical communication and computing, lensless microscopes, new types of quantum light sources, and high-density, high-resolution displays for augmented and virtual reality.

"As our work shows, it is critical to develop new engineering frameworks
for integration of nanomaterials into functional nanodevices. By moving
past the traditional boundaries of nanofabrication, materials engineering,
and device design, these techniques can allow us to manipulate matter
at the extreme nanoscale dimensions, helping us realize unconventional
device platforms important to addressing emerging technological needs,"
says Farnaz Niroui, the EE Landsman Career Development Assistant Professor
of Electrical Engineering and Computer Science (EECS), a member of the
Research Laboratory of Electronics (RLE), and senior author of a new
paper describing the work.

Niroui's co-authors include lead author Patricia Jastrzebska-Perfect,
an EECS graduate student; Weikun "Spencer" Zhu, a graduate student in
the Department of Chemical Engineering; Mayuran Saravanapavanantham,
Sarah Spector, Roberto Brenes, and Peter Satterthwaite, all EECS
graduate students; Zheng Li, an RLE postdoc; and Rajeev Ram, professor
of electrical engineering. The research will be published in Nature Communications.

Tiny crystals, huge challenges Integrating halide perovskites into
on-chip nanoscale devices is extremely difficult using conventional
nanoscale fabrication techniques. In one approach, a thin film of fragile perovskites may be patterned using lithographic processes, which require solvents that may damage the material. In another approach, smaller
crystals are first formed in solution and then picked and placed from
solution in the desired pattern.

"In both cases there is a lack of control, resolution, and integration capability, which limits how the material can be extended to nanodevices," Niroui says.

Instead, she and her team developed an approach to "grow" halide
perovskite crystals in precise locations directly onto the desired
surface where the nanodevice will then be fabricated.

Core to their process is to localize the solution that is used in the nanocrystal growth. To do so, they create a nanoscale template with
small wells that contain the chemical process through which crystals
grow. They modify the surface of the template and the inside of the
wells, controlling a property known as "wettability" so a solution
containing perovskite material won't pool on the template surface and
will be confined inside the wells.

"Now, you have these very small and deterministic reactors within which
the material can grow," she says.

And that is exactly what happens. They apply a solution containing halide perovskite growth material to the template and, as the solvent evaporates,
the material grows and forms a tiny crystal in each well.

A versatile and tunable technique The researchers found that the
shape of the wells plays a critical role in controlling the nanocrystal positioning. If square wells are used, due to the influence of nanoscale forces, the crystals have an equal chance of being placed in each of
the well's four corners. For some applications, that might be good
enough, but for others, it is necessary to have a higher precision in
the nanocrystal placement.

By changing the shape of the well, the researchers were able to engineer
these nanoscale forces in such a way that a crystal is preferentially
placed in the desired location.

As the solvent evaporates inside the well, the nanocrystal experiences
a pressure gradient that creates a directional force, with the exact
direction being determined using the well's asymmetric shape.

"This allows us to have very high precision, not only in growth, but
also in the placement of these nanocrystals," Niroui says.

They also found they could control the size of the crystal that forms
inside a well. Changing the size of the wells to allow more or less
growth solution inside generates larger or smaller crystals.

They demonstrated the effectiveness of their technique by fabricating
precise arrays of nanoLEDs. In this approach, each nanocrystal is made
into a nanopixel which emits light. These high-density nanoLED arrays
could be used for on-chip optical communication and computing, quantum
light sources, microscopy, and high-resolution displays for augmented
and virtual reality applications.

In the future, the researchers want to explore more potential applications
for these tiny light sources. They also want to test the limits of how
small these devices can be, and work to effectively incorporate them
into quantum systems.

Beyond nanoscale light sources, the process also opens up other
opportunities for developing halide perovskite-based on-chip nanodevices.

Their technique also provides an easier way for researchers to study
materials at the individual nanocrystal level, which they hope will
inspire others to conduct additional studies on these and other unique materials.

"Studying nanoscale materials through high-throughput methods often
requires that the materials are precisely localized and engineered at
that scale," Jastrzebska-Perfect adds. "By providing that localized
control, our technique can improve how researchers investigate and tune
the properties of materials for diverse applications." This work was supported, in part, by the National Science Foundation and the MIT Center
for Quantum Engineering.

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========================================================================== Journal Reference:
1. Patricia Jastrzebska-Perfect, Weikun Zhu, Mayuran
Saravanapavanantham,
Zheng Li, Sarah O. Spector, Roberto Brenes, Peter F. Satterthwaite,
Rajeev J. Ram, Farnaz Niroui. On-site growth of perovskite
nanocrystal arrays for integrated nanodevices. Nature
Communications, 2023; 14 (1) DOI: 10.1038/s41467-023-39488-0 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2023/07/230706124613.htm

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