• Iron-rich rocks unlock new insights into

    From ScienceDaily@1:317/3 to All on Thu May 25 22:30:40 2023
    Iron-rich rocks unlock new insights into Earth's planetary history
    Study suggests ancient microorganisms helped cause massive volcanic
    events

    Date:
    May 25, 2023
    Source:
    Rice University
    Summary:
    A new study suggests iron-rich ancient sediments may have helped
    cause some of the largest volcanic events in the planet's history.


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    FULL STORY ========================================================================== Visually striking layers of burnt orange, yellow, silver, brown
    and blue-tinged black are characteristic of banded iron formations,
    sedimentary rocks that may have prompted some of the largest volcanic
    eruptions in Earth's history, according to new research from Rice
    University.

    The rocks contain iron oxides that sank to the bottom of oceans long ago, forming dense layers that eventually turned to stone. The study published
    this week in Nature Geoscience suggests the iron-rich layers could connect ancient changes at Earth's surface -- like the emergence of photosynthetic
    life -- to planetary processes like volcanism and plate tectonics.

    In addition to linking planetary processes that were generally thought
    to be unconnected, the study could reframe scientists' understanding
    of Earth's early history and provide insight into processes that could
    produce habitable exoplanets far from our solar system.

    "These rocks tell -- quite literally -- the story of a changing
    planetary environment," said Duncan Keller, the study's lead author and
    a postdoctoral researcher in Rice's Department of Earth, Environmental
    and Planetary Sciences.

    "They embody a change in the atmospheric and ocean chemistry."
    Banded iron formations are chemical sediments precipitated directly
    from ancient seawater rich in dissolved iron. Metabolic actions of microorganisms, including photosynthesis, are thought to have facilitated
    the precipitation of the minerals, which formed layer upon layer over
    time along with chert (microcrystalline silicon dioxide). The largest
    deposits formed as oxygen accumulated in Earth's atmosphere about 2.5
    billion years ago.

    "These rocks formed in the ancient oceans, and we know that those
    oceans were later closed up laterally by plate tectonic processes,"
    Keller explained.

    The mantle, though solid, flows like a fluid at about the rate that
    fingernails grow. Tectonic plates -- continent-sized sections of the
    crust and uppermost mantle -- are constantly on the move, largely as a
    result of thermal convection currents in the mantle. Earth's tectonic
    processes control the life cycles of oceans.

    "Just like the Pacific Ocean is being closed today -- it's subducting
    under Japan and under South America -- ancient ocean basins were destroyed tectonically," he said. "These rocks either had to get pushed up onto continents and be preserved -- and we do see some preserved, that's
    where the ones we're looking at today come from -- or subducted into
    the mantle." Because of their high iron content, banded iron formations
    are denser than the mantle, which made Keller wonder whether subducted
    chunks of the formations sank all the way down and settled in the lowest
    region of the mantle near the top of Earth's core. There, under immense temperature and pressure, they would have undergone profound changes as
    their minerals took on different structures.

    "There's some very interesting work on the properties of iron oxides at
    those conditions," Keller said. "They can become highly thermally and electrically conductive. Some of them transfer heat as easily as metals
    do. So it's possible that, once in the lower mantle, these rocks would
    turn into extremely conductive lumps like hot plates." Keller and his co-workers posit that regions enriched in subducted iron formations
    might aid the formation of mantle plumes, rising conduits of hot rock
    above thermal anomalies in the lower mantle that can produce enormous
    volcanoes like the ones that formed the Hawaiian Islands. "Underneath
    Hawaii, seismological data show us a hot conduit of upwelling mantle,"
    Keller said.

    "Imagine a hot spot on your stove burner. As the water in your pot is
    boiling, you'll see more bubbles over a column of rising water in that
    area. Mantle plumes are sort of a giant version of that." "We looked at
    the depositional ages of banded iron formations and the ages of large
    basaltic eruption events called large igneous provinces, and we found
    that there's a correlation," Keller said. "Many of the igneous events --
    which were so massive that the 10 or 15 largest may have been enough to resurface the entire planet -- were preceded by banded iron formation deposition at intervals of roughly 241 million years, give or take 15
    million. It's a strong correlation with a mechanism that makes sense."
    The study showed that there was a plausible length of time for banded
    iron formations to first be drawn deep into the lower mantle and to then influence heat flow to drive a plume toward Earth's surface thousands
    of kilometers above.

    In his effort to trace the journey of banded iron formations, Keller
    crossed disciplinary boundaries and ran into unexpected insights.

    "If what's happening in the early oceans, after microorganisms chemically change surface environments, ultimately creates an enormous outpouring
    of lava somewhere else on Earth 250 million years later, that means these processes are related and 'talking' to each other," Keller said. "It also
    means it's possible for related processes to have length scales that are
    far greater than people expected. To be able to infer this, we've had to
    draw on data from many different fields across mineralogy, geochemistry, geophysics and sedimentology." Keller hopes the study will spur further research. "I hope this motivates people in the different fields that it touches," he said. "I think it would be really cool if this got people
    talking to each other in renewed ways about how different parts of the
    Earth system are connected." Keller is part of the CLEVER Planets:
    Cycles of Life-Essential Volatile Elements in Rocky Planets program,
    an interdisciplinary, multi-institutional group of scientists led by
    Rajdeep Dasgupta, Rice's W. Maurice Ewing Professor of Earth Systems
    Science in the Department of Earth, Environmental and Planetary Sciences.

    "This is an extremely interdisciplinary collaboration that's looking at
    how volatile elements that are important for biology -- carbon, hydrogen, nitrogen, oxygen, phosphorus and sulfur -- behave in planets, at how
    planets acquire these elements and the role they play in potentially
    making planets habitable," Keller said.

    "We're using Earth as the best example that we have, but we're trying to
    figure out what the presence or absence of one or some of these elements
    might mean for planets more generally," he added.

    Cin-Ty Lee, Rice's Harry Carothers Wiess Professor of Geology, Earth, Environmental and Planetary Sciences, and Dasgupta are co-authors on
    the study.

    Other co-authors are Santiago Tassara, an assistant professor at Bernardo O'Higgins University in Chile, and Leslie Robbins, an assistant professor
    at the University of Regina in Canada, who both did postdoctoral work
    at Yale University, and Yale Professor of Earth and Planetary Sciences
    Jay Ague, Keller's doctoral adviser.

    NASA (80NSSC18K0828) and the Natural Sciences and Engineering Research
    Council of Canada (RGPIN-2021-02523) supported the research.

    * RELATED_TOPICS
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    ========================================================================== Story Source: Materials provided by Rice_University. Original written
    by Silvia Cernea Clark.

    Note: Content may be edited for style and length.


    ========================================================================== Journal Reference:
    1. Duncan S. Keller, Santiago Tassara, Leslie J. Robbins, Cin-Ty
    A. Lee, Jay
    J. Ague, Rajdeep Dasgupta. Links between large igneous province
    volcanism and subducted iron formations. Nature Geoscience, 2023;
    DOI: 10.1038/ s41561-023-01188-1 ==========================================================================

    Link to news story: https://www.sciencedaily.com/releases/2023/05/230525140951.htm

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