Detecting stressed-out polymer films, gels before they break

Date:
February 23, 2022
Source:
American Chemical Society
Summary:
Stretchy films and squishy gels help make wearable electronics,
soft robotics and biocompatible tissues a reality. But too much
force can cause these polymers to break apart without warning. To
detect stress before it's too late, researchers show they have
designed a compound with 'wings' that makes these materials change
color when they are stretched or crushed.



FULL STORY ========================================================================== Stretchy films and squishy gels help make wearable electronics, soft
robotics and biocompatible tissues a reality. But too much force can cause these polymers to break apart without warning. To detect stress before
it's too late, researchers reporting in the Journal of the American
Chemical Society show they have designed a compound with "wings" that
makes these materials change color when they are stretched or crushed.


========================================================================== Plasticky films and polymer gels -- soft 3D networks filled with liquids
-- can be bendable, stretchable or compressible. And while most polymer
films only snap apart when pulled too far, many gels aren't very strong, cracking under relatively small amounts of pressure. Yet there isn't
a way to predict how tough the spongy material will be. In previous
research, Shohei Saito and colleagues developed V-shaped molecules,
known as flapping molecular (FLAP) force probes. FLAPs have two side
structures resembling wings that flatten under pressure, causing a color
change from blue to green fluorescence. This probe worked as expected when incorporated into a polyurethane film, but when added to a liquid-soaked polymer gel, the compound spontaneously turned fluorescent green without
any external force. So, Saito and Takuya Yamakado set out to improve the
FLAP molecule so that it would accurately detect mechanical stresses in
both a polymer gel and a film.

The researchers modified their earlier version by replacing the two anthraceneimide wings with pyreneimide ones, attaching them to opposite
sides of the same flexible central cyclooctatetraene joint. When they
added the probe into a polymer film and stretched the material, its fluorescence shifted strongly from blue to green. It also produced a
color change that was visible to the naked eye. Next, the researchers incorporated the new FLAP probe into a polyurethane gel soaked in
an organic solvent, creating a yellow cylinder that fluoresced blue,
and then compressed the material. The cylinder's fluorescence became
measurably greener as more pressure was exerted. In their final test,
the researchers placed metal letters F-L-A-P on a rectangular block of
the gel.

They used maps of the green to blue fluorescence ratio to calculate the pressure each letter placed on the gel below, which ranged from 0 to 1
MPa. The researchers say this study could help them develop tougher gel materials and nanoscale tension probes for cell membranes.

The authors acknowledge funding from a Japan Science and Technology
Agency PRESTO (FRONTIER) grant, a Japan Science and Technology Agency
FOREST grant, a Japan Society for the Promotion of Science KAKENHI
grant, a Japan Society for the Promotion of Science Fellowship, the
Inoue Foundation for Science and the Toray Science Foundation.

Video: https://youtu.be/Lu4j3Qn8m0U ========================================================================== Story Source: Materials provided by American_Chemical_Society. Note:
Content may be edited for style and length.


========================================================================== Journal Reference:
1. Takuya Yamakado, Shohei Saito. Ratiometric Flapping Force Probe That
Works in Polymer Gels. Journal of the American Chemical Society,
2022; 144 (6): 2804 DOI: 10.1021/jacs.1c12955 ==========================================================================

Link to news story: https://www.sciencedaily.com/releases/2022/02/220223085500.htm

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